Design, Fabrication and Functional Properties of Titanium Suboxide-Based Composites With Low Noble Metal Content for Electrocatalytic Applications

dc.contributor.authorKnysh, Valentina О.en
dc.contributor.authorZhemela, Heorhiien
dc.contributor.authorShmychkova, Olesia B.en
dc.contributor.authorLuk'yanenko, Tatiana V.en
dc.contributor.authorVelichenko, Oleksandr В.en
dc.date.accessioned2026-04-27T07:02:59Z
dc.date.issued2025
dc.descriptionValentina О. Knysh: ORCID 0000-0003-3024-3372; Heorhii Zhemela: ORCID 0009-0005-5106-0737; Olesia B. Shmychkova: ORCID 0000-0001-9490-9706; Tatiana V. Luk'yanenko: ORCID 0000-0001-9272-0301; Oleksandr В.Velichenko: ORCID 0000-0003-1076-9991en
dc.description.abstractENG: Fabrication, design and investigation of functional properties of composite materials based on titanium suboxides with low noble metal content for use in electrocatalysis has been investigated. The study particularly focuses on electrode coatings derived from titanium dioxide modified with platinum and palladium. The structural, electrocatalytic, and corrosion-resistant properties of these materials were systematically investigated. It was demonstrated that thermal treatment significantly enhances the catalytic efficiency of the coatings by reducing the oxygen evolution overpotential and improving the efficiency of hypochlorite synthesis. Optimal thermal treatment conditions (500 °C, 3 hours) were identi-fied, resulting in increased stability of the anodes containing Pt and Pd layers, as evidenced by a service life of 176 hours. The study highlights the potential of these composites for applications in oxygen evolution reactions and hypochlorite synthesis, owing to their high stability, selectivity, and cost-effectiveness.en
dc.description.sponsorshipUkrainian State University of Science and Technologiesen
dc.identifier.citationKnysh V. О., Zhemela H., Shmychkova O. B., Luk'yanenko T. V., Velichenko O. В. Design, Fabrication and Functional Properties of Titanium Suboxide-Based Composites With Low Noble Metal Content for Electrocatalytic Applications. Journal of Electrochemical Science and Engineering. 2025. Vol. 15 № 6. Р. 1–17. DOI: 10.5599/jese.2708en
dc.identifier.issn1847-9286
dc.identifier.urihttps://pub.iapchem.org/ojs/index.php/JESE/article/view/2708/2616en
dc.identifier.urihttps://crust.ust.edu.ua/handle/123456789/22081en
dc.language.isoen
dc.publisherJournal of Electrochemical Science and Engineeringen
dc.rightsCreative Commons Attribution (CC BY) licenseen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subjectTitanium compositesen
dc.subjectprecious metalsen
dc.subjectsemiconducting propertiesen
dc.subjectelectrocatalystsen
dc.subjectoxygen evolution reactionen
dc.subjecthypochlorite synthesisen
dc.subjectКФХuk_UA
dc.subject.classificationTECHNOLOGYen
dc.titleDesign, Fabrication and Functional Properties of Titanium Suboxide-Based Composites With Low Noble Metal Content for Electrocatalytic Applicationsen
dc.typeArticleen

Files

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
09_jESE_2708.pdf
Size:
1.68 MB
Format:
Adobe Portable Document Format

License bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description: