Browsing by Author "Protsenko, Vyacheslav S."
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Item Electrodeposition of Nanocrystalline Chromium–Carbon Alloys from Electrolyte Based on Trivalent Chromium Sulfate Using Pulsed Current(Springer, 2012) Protsenko, Vyacheslav S.; Danilov, Fedor I.; Gordiienko, Victor O.; Baskevich, Alexander S.; Artemchuk, Viktor V.EN: The effect of pulse parameters on the electrolysis current output, nanocrystals size, composition, hardness, friction coefficient and wear resistance of nanocrystalline coatings Cr-C, obtained from the sulfuric acid-based electrolyte salts Cr (III), comprising urea and formic acid. It is shown that coatings containing ~ 9% (wt.) carbon; current density and duty cycle do not affect the composition blocked. It was found that depending on the current output from the duty cycle when there is a maximum duty cycle ~ 1.05 ... 1.1, where the output current significantly exceeds the value realized in current-mode steady-state. It is shown that if the micro-hardness Cr-C deposits obtained at DC, is close to 850-900 HV, then using a pulsed electrolysis in certain modes may increase the microhardness up to ~ 1200-1300 HV. Found that the use of pulsed electrolysis can significantly reduce the coefficient of friction chrome-carbon cover (with steel counterbody) in conditions of dry friction and under boundary lubrication, and also increases the durability of precipitation.Item Electroplating of Wear-Resistant Nanocrystalline Coatings from a Bath Containing Basic Chromium(III) Sulfate (chrome tanning agent)(Pleiades Publishing, Ltd., 2013) Danilov, Felix I.; Protsenko, Vyacheslav S.; Gordiienko, Viktor O.; Baskevich, Aleksandr S.; Artemchuk, Viktor V.ENG: Regularities of the electroplating of chromium–carbon alloy coatings from a bath containing basic chromium(III) sulfate, carbamide, formic acid, sodium sulfate, aluminum sulfate, orthoboric acid, and sodium dodecyl sulfate are studied. Replacement of chromium sulfate as a source of trivalent chromium ions in the solution with basic chromium sulfate (chrome tanning agent) results in a decrease in the current density when metal deposition begins. As a result, the covering power of the bath increases. The effects discovered are determined by changes in the composition of the discharged chromium complexes. A certain excess of OH– groups in the inner sphere of electroactive chromium complexes results in acceleration of electroplat ing. The studied electrolyte based on chrome tanning agent enables one to produce thick high quality nanoc rystalline Cr–C alloy coatings with improved tribological characteristics.Item Improving Hardness and Tribological Characteristics of Nanocrystalline Cr-C Films Obtained from Cr(III) Plating Bath Using Pulsed Electrodeposition(Elsevier Science Publishing Company, Inc., 2012) Protsenko, Vyacheslav S.; Danilov, Fedor I.; Gordiienko, Victor O.; Baskevich, Alexander S.; Artemchuk, Viktor V.EN: Effect of pulsed electrodepostion on the nanocrystal size, composition, hardness, coefficient of friction and wear resistance was investigated for the Cr–C electrodeposits obtained from a trivalent chromium bath. The electrodeposits were shown to contain about 9% of carbon. Pulsed electrodeposition does not virtually affect the carbon content. At the same time, an increase in the off time duration leads to a decrease in the nanocrystals size. The hardness and wear parameters of the electrodeposits may be sufficiently improved when using pulsed current. For instance, at ton=toff=1 s, the hardness reaches the values of ~1200÷1300 HV (meanwhile, it is close to 850÷950 HV at a steady-state electrolysis).