Browsing by Author "Sybir, Artem"

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Analysis of Changes in Global Warming Potential during Enrichment and Production of Battery-Grade Graphite Using Electrothermal Fluidized Bed Technology
(IOP Publishing Ltd, 2024) Hubynskyi, Semen M.; Sybir, Artem; Fedorov, Serhii S.; Usenko, Andrii Yu.; Hubynskyi, Mykhailo V.; Vvedenska, Tetyana
ENG: The greenhouse gas emissions during the production of anode class graphite for the conditions of Ukraine have been calculated. Conventional technologies and technologies using electrothermal fluidized bed (EFB) for natural and synthetic graphite have been studied. Calculations are carried out with respect to the whole technological chain, starting from extraction and processing of raw materials and ending with finishing processing (coating). As a result, it is shown that the technology of using EFB for purification of natural graphite and graphitization of synthetic graphite is competitive in terms of global warming potential (GWP). In the production of natural graphite using thermal purification with EFB instead of chemical purification, emissions of greenhouse gases practically remain at the same level. At the same time, the use of acids is eliminated, and the environmental impact associated with them is reduced. Production of synthetic graphite of anodic quality in EFB furnaces allows to reduce greenhouse gases (GHG) emissions by 40-50% in comparison with traditional graphitization technologies in Acheson and Kastner furnaces. The effect is achieved by reducing energy and raw material consumption.
Electrically Heated Fluidized Bed for Graphite Purification: Heat Transfer and Electric Resistivity Models for Scale-Up
(Springer Nature, 2025) Ahmed, Imtiaz; Fedorov, Serhii S.; Sybir, Artem; Hubynskyi, Semen M.; Duchesne, Marc
ENG: Electrothermal purification is an effective method for achieving over 99.9 pct purity for graphite particles with minimal environmental impact. However, the lack of a suitable heat and electric resistivity model has hindered the scaling up of electrically heated fluidized bed (EHFB) reactors for graphite purification. In this study, three commercial natural graphite flake populations were tested in a bench-scale fluidized bed reactor at temperatures of up to 1000 °C. The experiments varied key parameters, including the graphite particle size, particle bed temperature, fluidization index, and electrode depth within the particle bed. Controlling the fluidized bed reactor at high temperatures requires an understanding of bed resistivity and how current flows throughout the EHFB system. The results show that fluidized bed resistivity decreases with temperature, with a diminished effect at higher temperatures. Smaller particles exhibit a higher resistance, likely due to a larger number of contact points required to pass current between the electrodes. In this study, a Finite Difference Method (FDM) model was developed using Visual Basic for Applications (VBA) in Excel®. Additionally, a Finite Element Method (FEM) model was created using COMSOL Multiphysics®. The FDM model assumes the current flows only radially, whereas the FEM model accounts for both radial and vertical current flow. The FDM model was validated against experimental data. Additionally, the FDM model was verified through a comparison with the FEM model. The FDM model showed good agreement with experimental resistance data and moderate agreement with power consumption, while the FEM model provided more accurate predictions by accounting for a detailed geometry and heat loss mechanisms. Achieving a uniform temperature distribution within the fluidized bed is influenced by the electrode’s contact area. Deeper immersion of the electrode enhances thermal uniformity and provides results that more closely match experimental observations.
Phenomena at Three-Phase Electroslag Remelting
(Springer Nature, 2021) Liu, Zhong-li; Medovar, Lev; Stovpchenko, Ganna; Petrenko, Volodymyr; Sybir, Artem; Volchenkov, Yev.
ENG: The electroslag remelting (ESR) process is widely used to produce high-quality ingots and billets for high-alloyed steels and alloys. Both the single-phase and three-phase alternating current diagram with bifilar and monofilar connection are in use for heavy ingot manufacturing. The numerical simulation of the three-phase bifilar circuit for the 120 t three-phase bifilar six-electrode ESR furnace at different variants of electric connection was presented and discussed. At the bifilar diagram of power supply, the geometrical location of electrodes in a mould holds critical importance for performances: the close location of bifilar pair electrodes provides the highest heat productivity, but the equidistant location of electrodes gives a much more uniform heat distribution. The monofilar mulit-electrode diagram of three-phase connection without phase shift shows the most uniform distribution of potential and heat generation as well as a favorable magnetic field that makes this kind the most promising for providing a high quality of heavy ingots.